Atom-atom interactions at and between metal surfaces at nonzero temperature
نویسندگان
چکیده
We have investigated the temperature-dependent Casimir-Polder interaction between two oscillators in the proximity of metal surfaces. The interaction near a single metal surface has much in common with the interaction in free space. However, at any finite temperature the long-range asymptote is equal to the hightemperature asymptote. This asymptote, which originates not from the n50 term in the Matsubara summation but from thermal population of the n.0 terms, is F(R)522kBTa0 /R6. This should be compared with the more rapidly decaying zero-temperature Casimir-Polder asymptote, F(R)'213\ca0 /(2pR7). The interaction in the midplane between two metallic surfaces is very different. The nonretarded interaction decreases exponentially and the interaction is dominated by an enhanced Casimir-Polder-like asymptote. At large separations this asymptote also decays exponentially. For any relevant temperatures the long-range asymptote is no longer equal to the high-temperature limit. In other words crossover to a classical limit found for the longrange interaction in free space, and on a metal surface, is not always valid in a narrow cavity.
منابع مشابه
Comparison of metal additives and Boron atom on MgH2 absorbing-desorbing characteristics using calculated NQCCs
Using ab initio calculations, the hydrogen desorption from Magnesium hydride (MgH2) was studied. We presented the calculated nuclear quadrupole coupling constants (NQCCs) of hydrogen atom in various systems of MgH2. The effect of interactions of some metal atoms as well as Boron atom with MgH2 host matrix; (MgH2+M) nanostructures (M=Al, Ti, V, Fe, Ni ...
متن کاملComparison of metal additives and Boron atom on MgH2 absorbing-desorbing characteristics using calculated NQCCs
Using ab initio calculations, the hydrogen desorption from Magnesium hydride (MgH2) was studied. We presented the calculated nuclear quadrupole coupling constants (NQCCs) of hydrogen atom in various systems of MgH2. The effect of interactions of some metal atoms as well as Boron atom with MgH2 host matrix; (MgH2+M) nanostructures (M=Al, Ti, V, Fe, Ni ...
متن کاملua nt - p h / 06 01 03 1 v 1 5 J an 2 00 6 Dependences of the Casimir - Polder interaction between an atom and a cavity wall on atomic and material properties
The Casimir-Polder and van der Waals interactions between an atom and a flat cavity wall are investigated under the influence of real conditions including the dynamic polarizability of the atom, actual conductivity of the wall material and nonzero temperature of the wall. The cases of different atoms near metal and dielectric walls are considered. It is shown that to obtain accurate results for...
متن کاملCharacteristics of the Temporal Behavior of Entanglement between Photonic Binomial Distributions and a Two-Level Atom in a Damping Cavity
In the present study, temporal behavior of entanglement between photonic binomial distributions and a two-level atom in a leaky cavity, in equilibrium with the environment at a temperature T, is studied. In this regard, the master equation is solved in the secular approximation for the density matrix, when the initial photonic distribution is binomial, while the atomic states obey the Boltzmann...
متن کاملTheoretical studies on corrosion inhibition of N-aroyl-N’-aryl thiourea derivatives using conceptual DFT approach
In this paper, quantum chemical parameters at density functional theory (DFT) B3LYP/6-31G** (d,p) level of theory were calculated for three organic corrosion inhibitors [N-benzoyl-N-(p-aminophenyl) thiourea, N-benzoyl-N-(thiazole) thiourea and N-acetyl-N-(dibenzyl) thiourea. The calculated molecular descriptors such as the HOMO, LUMO, dipole moment, chemical potential (μ), chemical hardness (ղ)...
متن کاملذخیره در منابع من
با ذخیره ی این منبع در منابع من، دسترسی به آن را برای استفاده های بعدی آسان تر کنید
عنوان ژورنال:
دوره شماره
صفحات -
تاریخ انتشار 2001